Dynamic doping and degradation in sandwich-type light-emitting electrochemical cells.

نویسندگان

  • Sebastian B Meier
  • David Hartmann
  • Daniel Tordera
  • Henk J Bolink
  • Albrecht Winnacker
  • Wiebke Sarfert
چکیده

Photoluminescence spectroscopy has been performed in situ during device operation and after switch-off on ionic transition metal complex (iTMC)-based sandwich-type light-emitting electrochemical cells (LECs). It is demonstrated that the photoluminescence of the LECs decreases with increasing operating time. For operating times up to three hours the decline in photoluminescence is fully recoverable after switching off the bias. These results imply that doping of the iTMC layer is responsible, not only, for the turn-on of LECs but also for their lifetimes.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 14 31  شماره 

صفحات  -

تاریخ انتشار 2012